The SAM C20 has several different power supply pins:
The same voltage must be applied to both VDDIN and VDDANA. This common voltage is referred to as VDD in the datasheet. VDDIO must always be less than or equal to VDDIN.
The ground pins, GND, are common to VDDCORE, VDDIO and VDDIN. The ground pin for VDDANA is GNDANA.
For decoupling recommendations for the different power supplies, refer to the schematic checklist.