The Atmel SAM L22 has several different power supply pins:
VDDANA powers I/O lines and the ADC, AC, LCD, and PTC. Voltage is 1.62V to 3.63V
The same voltage must be applied to both VDDIO and VDDANA. This common voltage is referred to as VDD in the datasheet.
The ground pins, GND, are common to VDDCORE, and VDDIO. The ground pin for VDDANA is GNDANA.
For decoupling recommendations for the different power supplies, refer to the schematic checklist.